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The Ultimate Guide to Optical Windows

Author: Morgan

Aug. 12, 2024

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The Ultimate Guide to Optical Windows

VIS are a more cost-effective, specific option for use in the small range of visible light from 400-700nm. A UV window would work in similar applications but Optical Glass is a more specific, economical choice. N-BK7 is the material most commonly referred to by the name Optical Glass and features a transmission range of 350-2,000nm.

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A VIS window is a common tool for use in imaging/display systems as well as a standard base substrate for use with mirror and filter coatings. Featuring a high index of refraction, high transmission and a high standard of material purity, these windows are often a crucial component in various optical systems. Additionally, N-BK7 has a high degree of stain resistance

IR Windows

The extended family of IR windows encompasses the largest and most frequently used assortment of optical windows. You can visit the full family of optical windows on the Firebird Optics website.

Each particular window has its own unique property and transmission profile, which are needed for specialized applications. We will break down why you might be interested in each of these types of windows. Each material features a link which delves into more of the material specifics:

Barium Fluoride (BaF2)- features transmission from deep in the UV from 200nm-12μm, BaF2 can be used in multiple setups in the UV, VIS and IR range. Its main properties include resistance to high-energy radiation and its low index of refraction. AR coatings are often not needed.

Calcium Fluoride (CaF2)- is very similar to BaF2 in terms of its high damage threshold, low index of refraction and low absorption coefficient. CaF2's main standout is its outstanding transmission range of 130nm-9.5μm, which dips even deeper into the UV range and farther out into the IR range than UV Fused Silica. Like BaF2 it is mostly used in laser and cryogenic applications.

Germanium (Ge)- Germanium's standout property is its low dispersion, making it top choice for low power CO2 laser applications where a focused beam with minimal scattering is a must. Additionally, with its 2-16μm range, no unwanted radiation from the UV, VIS or even most of the NIR range can interfere with measurements. Germanium also has remarkable chemical properties and is inert to air, water, alkalis and many acids.

Potassium Bromide (KBr)- a mainstay in FTIR spectroscopy, KBr is sought after for its gigantic transmission range of 250nm all the way out to 26μm. KBr will withstand high temperatures up to 300ºC and mechanical shocks but care must be taken to avoid moist environments, which degrade the material.

Potassium Chloride (KCl)- often used interchangeably with KBr due to its similar transmission properties (210-20μm), KCl might be chosen over KBr due to its high damage thresholds and low index of refraction. Similar to Germanium, KCl is ideal for low-power CO2 laser applications but unlike Germanium, it can be used in the UV, VIS and NIR range.

Sapphire (Al2O3)- with a large transmission range of 150nm-4.5µm sapphire is a good generalist but where sapphire truly shines is its material robustness. You can use sapphire in almost any harsh environment and it will take the punishment. From extreme resistance to thermal conductivity, a high dielectric constant and chemical resistance, sapphire will take almost anything thrown at it and ask for seconds. Only behind diamond in terms of material hardness but unlike diamond can be made extremely thin, which further improves transmission.

Sodium Chloride (NaCl)- NaCl is the closest to a disposable option you'll find the IR window family. Since the window is essentially table salt, as you may imagine, it is sensitive to water and thermal shocks. With a wavelength range of 250-20μm, its main feature is that it is a cost-effective, wide range FTIR generalist.

Zinc Selenide (ZnSe)- The main reason to use a ZnSe window is in a high power Co2 laser system. High resistance to thermal shock, low absorption coefficient and low dispersion properties make it so you can concentrate high energy radiation and bring it to a focused, minimally scattered point through this window. Care must be taken as the material is soft and susceptible to scratches. ZnSe is not recommended for use in harsh environments. Get yourself a sapphire window instead!

Optical Glass | Products

Glass is not just a transparent solid material. Glass is a very homogeneous material among many solid materials and has isotropic properties due to its random structure. In addition, being an inorganic material, it has high durability, which makes it different from other transparent materials. The characteristics can be continuously tuned by designing its composition, in other words, by changing the ratio of various elements. Optical glass is a glass material developed by taking full advantage of these characteristics and is used in various optical components including lenses.

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Structure and Principle of Optical Glass

Glass has a long history and was already being used by mankind about 5,000 years ago. At first, it was valued as jewelry because it has clear transparency, develops a vivid color, and shines when exposed to light. The brightness and color of glass are due to the characteristics of glass, such as its transparency and refractive index, and optical glass makes use of these characteristics. Transparency and refractive index are two important parameters of optical glass. They will be explained later.

At present, an understanding of the physical properties of glass has been deepened, and in addition to the indices of optical properties, solubility at high temperatures and formability when softened are also taken into account when designing glass. For example, various glass products around us are mainly made from silica sand, which is mainly composed of silica (SiO2). Silica sand melts at a very high temperature (over 1,700°C). So, soda ash (Na2CO3) is usually added to lower the melting point and lime (CaO) is added to the ingredients to make the glass insoluble in water. This glass is called soda-lime glass and is often used in windows. In this way, we can make glass having various characteristics by adding other elements to the predominant ingredient, silica.

Glass network structure at the atomic level
Silica has a strong covalent bond of Si-O, but when additives such as Na are added, the covalent bond breaks and the properties change. Atoms in the network structure are arranged randomly with no regularity like a crystal, and such a structure is called amorphous. For this reason, whatever direction light goes in glass, it propagates through homogeneous crystal fields, and such high homogeneity is one of the important characteristics of optical glass.

1. Transparency

When you look at some scenery through glass, you can see things on the other side clearly. This is because the glass transmits the visible light that has passed through an object. Visible light is a form of electromagnetic wave with a wavelength normally in the range of 380 nm to 780 nm that can be recognized by the human eye. Various wavelengths are used in the optical field. For example, ultraviolet light is used for sterilization, near-infrared light is used for sensing and optical communication, and far-infrared light is used for thermal cameras and night vision cameras. When we say optical glass is transparent, that means the glass has high transmittance in the wavelength range of the relevant application.

Wavelength ranges of electromagnetic waves and their general names.
Light is a form of electromagnetic wave, and each wave has a wavelength (the length of a period of an electromagnetic wave). Human eyes can generally sense only light in the wavelength range called visible light rays, but optical glass and its processed products handle a wide range of light rays (electromagnetic radiation), including X-rays and microwaves, depending on the application.

The transparency of glass depends on the composition of the element used in the glass. In addition to that, it is important to control absorption and the scattering of light to achieve high transparency. For example, ordinary window glass contains iron in its composition, so it is slightly green even though it is transparent. This is due to the absorption of iron ions in the glass. Optical glass is designed to reduce such absorption by impurities. Even micron-size foreign matters inside the glass scatter light rays there, reducing the transparency of the glass. Some types of optical glass actively utilize absorption and scattering caused by additives and impurities.

Conceptual image of light rays passing through glass.
Light entering glass is first partially reflected on the surface and the rest enters the interior. While it is propagating through the glass, if additives that absorb light are present in the glass, part of the light is absorbed, and if additives or imprities that scatter light are present, the light is scattered to random directions. When the light reaches the opposite side, part of the light is reflected again, and the remaining light comes out of the glass as transmitted light.

2. Refractive index

Refractive index is one of the most basic indices of optical properties of glass, along with transparency. The refractive index of glass is determined by its composition. As its name implies, it influences the refractive angle of the light. In addition to that, reflectance and transmittance of the glass are also dependent on the refractive index. The refractive index is the most fundamental characteristic that indicates the interaction between light and the glass and is the basis of the optical behavior of glass.
The most familiar application of glass substrates with different refractive indices is the camera lens unit. Recently, optical waveguide substrates for AR/MR glasses have also been commercialized using the high optical confinement properties of high-refractive-index glass.

&#; Refraction condition (air to glass)

&#; Refraction condition (glass to air)

&#; Total reflection condition

Refraction and total reflection of light traveling between different media (e.g., air and glass).
When a light ray travels from the air to the inside of glass or from the inside of glass to the air, it does not go straight but changes its direction of travel, and this phenomenon is called refraction. The refractive index of a material is expressed as the ratio of the change in angle that happens when a light ray enters the material from a vacuum; the higher the refractive index, the greater the angular change. When a light ray travels from air with a low refractive index to glass with a high refractive index, the angle of the ray going out of the interface (refraction angle) is smaller than the angle of the ray coming into the interface (incidence angle). On the other hand, when a light ray travels from glass with a high refractive index into air with a low refractive index, the refraction angle becomes larger than the incidence angle. If the incidence angle of a light ray gets larger when it travels to air with a low refractive index from glass with a high refractive index, the refraction angle reaches 90°; that is, the light ray is totally reflected without entering the air. The angle at which this total reflection occurs is called the critical angle. The higher the refractive index of the glass, the smaller the critical angle and the wider the angle range of total reflection. That means, the glass has a strong light-confinement effect.

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